Abstract: Conventional lithium-ion secondary batteries have been widely used in portable electronic devices and are now developed for large-scale applications in hybrid-type electric vehicles and stationary-type distributed power sources. However, there are inherent safety issues associated with thermal management and combustible organic electrolytes in such battery systems. The demands for batteries with high energy and power densities make these issues increasingly important. All-solid-state lithium batteries based on solid-state polymer and inorganic electrolytes are leak-proof and have been shown to exhibit excellent safety performance, making them a suitable candidate for the large-scale applications. This paper presents a brief review of the state-of-the-art development of all-solid-state lithium batteries including working principles, design and construction, and electrochemical properties and performance. Major issues associated with solid-state battery technologies are then evaluated. Finally, remarks are made on the further development of all-solid-state lithium cells.

Key words: energy storage, all-solid-state lithium-ion cell, solid electrolyte, interface modification [1] Zhang Wenliang(张文亮),Wu Bin(武斌),Li Wufeng(李武峰),Lai Xiaokang(来小康). Discussion on development trend of battery electric vehicles in China and its energy supply mode[J]. Power System Technology (电网技术),2009,33(4):1-5.
[2] Hu Yingying(胡英瑛),Wen Zhaoyin(温兆银),Rui Kun(芮琨),Wu Xiangwei(吴相伟). State-of-the-art research and development status of sodium batteries[J]. Energy Storage Science and Technology (储能科学与技术),2013,2(2):81-90.
[3] Peng Jiayue(彭佳悦),Zu Chenxi(祖晨曦),Li Hong(李泓). Fundamental scientific aspects of lithium batteries(I) Thermodynamic calculations of theoretical energy densities of chemical energy storage systems[J]. Energy Storage Science and Technology (储能科学与技术),2013,2(1):55-62.
[4] Zhang Wenliang(张文亮),Qiu Ming(丘明),Lai Xiaokang(来小康). Application of energy storage technologies in power grids[J]. Power System Technology (电网技术),2008,32(7):1-9.
[5] Lu Xia(卢侠),Li Hong(李泓). Fundamental scientific aspects of lithium batteries(II) Defect chemistry in batteries materials[J]. Energy Storage Science and Technology (储能科学与技术),2013,2(2):157-164.
[6] Wen Zhaoyin(温兆银). Sodium sulfur cell and its energy storage application[J]. Shanghai Energy Conservation( 上海节能),2007(2):7-10.
[7] Zhang Huamin(张华民),Zhou Hantao(周汉涛),Zhao Ping(赵平),Yi Baolian(衣宝廉). Actuality and prospect of energy storage technologies[J]. Energy Engineering (能源工程),2005,1(3):1-7.
[8] Hu Xuejie(黄学杰). Li-ion battery and its key materials[J]. Materials China( 中国材料进展),2010,29(8):46-52.
[9] Zhao Xinbing(赵新兵),Xie Jian(谢健). Recent development of LiFePO 4 cathode materials for lithium-ion batteries[J]. Chinese Journal of Mechanical Engineering (机械工程学报),2007,43(1):69-76.
[10] Xu X X,Wen Z Y,Wu J G,Yang X L. Preparation and electrical properties of Li 1.4 Al 0.4 Ti 1.6 (PO 4 ) 3 glass-ceramics by the citric acid-assisted sol-gel method[J]. Solid State Ionics ,2007,178(1-2):29-34.
[11] Xu X X,Wen Z Y,Yang X L,Zhang J C,Gu Z H. High lithium ion conductivity glass-ceramics in Li 2 O-Al 2 O 3 -TiO 2 -P 2 O 5 from nanoscaled glassy powders by mechanical milling[J]. Solid State Ionics ,2006,177(26-32):2611-2615.
[12] Liu Wenyuan(刘文元),Fu Zhengwen(傅正文),Qin Qizong(秦启宗). Studies on lithium phosohorous oxynitride electrolyte thin films and a new all-solid-state thin film lithium battery[J]. Acta Chimica Sinica (化学学报),2004(22):2223-2227.
[13] Baba M,Kumagai N,Fujita N, et al. Fabrication and electrochemical characteristics of all-solid-state lithium-ion rechargeable batteries composed of LiMn 2 O 4 positive and V 2 O 5 negative electrodes[J]. Journal of Power Sources ,2001,7(97-98):798-800.
[14] Qiu Weili(邱玮丽), Yang Qinghe(杨清河), Ma Xiaohua(马晓华), et al . Research on PEO-based dry solid polymer electrolytes for rechargeable lithium batterises[J]. Chinese Journal of Power Sources (电池技术),2004,28(7):440-448
[15] Zhang S S,Ervin M H,Xu K,Jow T R. Microporous poly (acrylonitrile-methyl methacrylate) membrane as a separator of rechargcable lithium battery[J]. Electrochimica Acta ,2004,49(20):3339-3345.
[16] Kuwata N,Kawamura J,Toribami K,Hattori T. In solid state ionics:the science and technology of ions in motion[C]//(proc. 9th Asian Conf. solid state ionics),World Sci.Publ.Co.,Singapore,2004,637.
[17] Kuwata N,Kawamura J,Toribami K,Hattori T,Sata N. Thin-film lithium-ion battery with amorphous solid electrolyte fabricated by pulsed laser deposition[J]. Electrochemistry Communications ,2004,6(4):417-420.
[18] Bates J B,Dudney N J,Neudecker B, et al . Thin-film lithium and lithium-ion batteries[J]. Solid State Ionics ,2000,135(1-4):33-45.
[19] Dudney N J,Bates J B,Zuhr R A,Young S,Robertson J D,Jun H P,Hackney S A. Nanocrystalline Li x Mn 2- y O 4 cathodes for solid-state thin-film rechargeable lithium batteries[J]. Journal of the Electrochemical Society ,1999,146(7):2455-2464.
[20] Neudecker B J,Dudney N J,Bates J B. "Lithium-free" thin-film battery with in situ plated li anode[J]. Journal of the Electrochemical Society ,2000,147(2):517-523.
[21] Neudecker B J,Zuhr R A,Robertson J D,Bates J B. Lithium manganese nickel oxides Li x (Mn y Ni 1- y ) 2- x O 2 I. Synthesis and characterization of thin films and bulk phases[J]. Journal of the Electrochemical Society ,1998,145(12):4148-4159.
[22] Neudecker B J,Zuhr R A,Robertson J D,Bates J B. Lithium manganese nickel oxides Li x (Mn y Ni 1- y ) 2- x O 2 (II) Electrochemical studies on thin-film batteries[J]. Journal of the Electrochemical Society ,1998,145(12):4160-4168.
[23] Neudecker B J,Zuhr R A,Bates J B. Lithium silicon tin oxynitride(Li y SiTON):High-performance anode in thin-film lithium-ion batteries for microelectronics[J]. Journal of Power Sources ,1999,9(81-82):27-32.
[24] MacGlashan G S,Andreev Y G,Bruce P. Structure of the polymer electrolyte poly (ethylene oxide) 6 :LiAsF 6 [J]. Nature ,1999,398:792-794.
[25] Croce F,Appetecchi G B,Persi L,Scrosati B. Nanocomposite polymer electrolytes for lithium batteries[J]. Nature ,1998,394:456-458.
[26] Kariatsumari K. Next-gen batteries going all-solid:Demand for large size batteries in EVs and stationary use driving development[N]. Nikkei Electronics Asia ,2010-07-01.
[27] 辛江. Kolibri电池,让电动车畅通无阻[N]. 第一财经周刊,2011-11-16.
[28] Noriaki K,Kenji H,Yuichiro Y, et al . A lithium superionic conductor[J]. Nat. Mater. ,2011,10(9):682-687.
[29] Keiichi M,Akitoshi H,Masahiro T. Crystallization process for superionic Li 7 P 3 S 11 glass-ceramic electrolytes[J]. Journal of the American Ceramic Society ,2010,94(6):1779-1783.
[30] Liu Z C,Fu W J,Payzant E A, et al . Anomalous high ionic conductivity of nanoporous β-Li 3 PS 4 [J]. Journal of the American Chemical Society ,2013,135:975-978.
[31] 许晓雄,姚霞银,刘兆平,等. 全固态锂二次电池电解质材料,其制备方法及全固态锂二次电池:中国,201210050031.9[P]. 2012-02-29.
[32] Chen Liquan(陈立泉). Hybrid electric vehicles and their batteries[J]. Battery Bimonthly (电池),2000,30(3):98-100.
[33] Owens B B. Solid-state electrolytes:Overview of materials and applications during the last third of the twentieth century[J]. J ournal of Power Sources ,2000,90(1):2-8.
[34] Xu Xiaoxiong(许晓雄),Wen Zhaoyin(温兆银). Glass and glass-ceramics solid electrolytes for lithium-ion battery[J]. Journal of Inorganic Materials (无机材料学报),2005,20(1):21-26.
[35] Zhu X J,Shen O C,Xu X X, et al . Direct observation of lithium-ion transport under an electrical field in Li x CoO 2 nanograins[J]. Scientific Reports ,2013,3:1-8.
[36] Ohta N,Takada K,Zhang L Q,Ma R Z,Osada M,Sasaki T. Enhancement of the high-rate capability of solid-state lithium batteries by nanoscale interfacial modification[J]. Advanced Materials ,2006,18(17):2226-2229.
[37] Maier J. Nanoionics:Ion transport and electrochemical storage in confined systems[J]. Nature Materials ,2005,4(11):805-815.
[38] Xu X X,Takada K,Fukuda K, et al . Tantalum oxide nanomesh as self-standing one nanometre thick electrolyte[J]. Energy & Environmental Science ,2011,4(9):3509-3512.
[39] Xu X X,Takada K,Watanabe K,e t al . Self-organized core-shell structure for high-power electrode in solid-state lithium batteries[J]. Chemistry of Materials ,2011,23(17):3798-3804.
[40] Armand M,Tarascon J M. Building better batteries[J]. Nature ,2008,451:652-657.
[41] Croce F,Appetecchi G B,Persi L,Scrosati B. Nanocomposite polymer electrolytes for lithium batteries[J]. Nature ,1998,394:456-458.
[42] Sasaki T,Watanabe M,Hashizume H,Yamada H,Nakazawa H. Macromolecule-like aspects for a colloidal suspension of an exfoliated titanate. pairwise association of nanosheets and dynamic reassembling process initiated from it[J]. Journal of the American Chemical Society ,1996,118(35):8329-8335.
[43] Omomo Y,Sasaki T,Wang L Z,Watanabe M. Fabrication and characterization of multilayer ultrathin films of exfoliated MnO 2 nanosheets and polycations[J]. Journal of the American Chemical Society ,2003,15(15):2873-2878.
[44] Osada M,Ebina Y,Takada K,Sasaki T. Gigantic magneto-optical effects in multilayer assemblies of two-dimensional titania nanosheets[J]. Advance Materials ,2006,18(3):295-299.
[45] Osada M,Ebina Y,Funakubo H,Yokoyama S,Kiguchi T,Takada K,Sasaki T. High- κ dielectric nanofilms fabricated from titania nanosheets[J]. Advance Materials ,2006,18(8):1023-1027. 姚祯, 张琦, 王锐, 刘庆华, 王保国, 缪平. 生物质衍生碳材料在全钒液流电池电极方面的应用 [J]. 储能科学与技术, 2022, 11(7): 2083-2091. 时雨, 张忠, 杨晶莹, 钱薇, 李昊, 赵祥, 杨欣桐. 储能电池系统提供 AGC 调频的机会成本建模与市场策略 [J]. 储能科学与技术, 2022, 11(7): 2366-2373. 曾伟, 熊俊杰, 李建林, 马速良, 武亦文. 基于权重自适应鲸鱼优化算法的多能系统储能电站最优配置 [J]. 储能科学与技术, 2022, 11(7): 2241-2249. 韩健民, 薛飞宇, 梁双印, 乔天舒. 模糊控制优化下的混合储能系统辅助燃煤机组调频仿真 [J]. 储能科学与技术, 2022, 11(7): 2188-2196. 冯国会, 王天雨, 王刚. 封装方式对相变水箱蓄放热性能影响模拟分析 [J]. 储能科学与技术, 2022, 11(7): 2161-2176. 董树锋, 刘灵冲, 唐坤杰, 赵海祺, 徐成司, 林立亨. 基于 Simulink 和低代码控制器的储能控制实验教学方法 [J]. 储能科学与技术, 2022, 11(7): 2386-2397. 鲁志颖, 江杉, 李全龙, 马可心, 傅腾, 郑志刚, 刘志成, 李淼, 梁永胜, 董知非. 全钒液流电池在充电结束搁置阶段的开路电压变化 [J]. 储能科学与技术, 2022, 11(7): 2046-2050. 郭雨涵, 郁丹, 杨鹏, 王子绩, 王金涛. 基于贪婪算法的分布式储能系统容量优化配置方法 [J]. 储能科学与技术, 2022, 11(7): 2295-2304. 袁性忠, 胡斌, 郭凡, 严欢, 贾宏刚, 苏舟. 欧盟储能政策和市场规则及对我国的启示 [J]. 储能科学与技术, 2022, 11(7): 2344-2353. 刘国静, 李冰洁, 胡晓燕, 岳芬, 徐际强. 澳大利亚储能相关政策与电力市场机制及对我国的启示 [J]. 储能科学与技术, 2022, 11(7): 2332-2343. 杨孝杰, 王海云, 蒋中川, 宋章华. 应用于飞轮储能的 BLDC 电机功率双向流动策略设计 [J]. 储能科学与技术, 2022, 11(7): 2233-2240. 李洪涛, 张帅, 李旭东, 纪运广, 孙明旭, 李欣. 单罐式储能换热系统在热风无纺布工艺中的应用 [J]. 储能科学与技术, 2022, 11(7): 2250-2257. 吴田, 林闽城, 海浩, 孙海渔, 温兆银, 马福元. 面向一次调频的镍氢电池系统开发 [J]. 储能科学与技术, 2022, 11(7): 2213-2221. 徐光福, 姜淼, 王万纯, 魏阳, 侯炜. 大型储能电池短路故障分析与保护策略 [J]. 储能科学与技术, 2022, 11(7): 2222-2232. 张平, 康利斌, 王明菊, 赵广, 罗振华, 唐堃, 陆雅翔, 胡勇胜. 钠离子电池储能技术及经济性分析 [J]. 储能科学与技术, 2022, 11(6): 1892-1901. 凡注明本刊独家的版权为《储能科学与技术》所有，欢迎转载但请务必注明来源。如果本文侵犯您的权益，请联系本站删除！
凡注明“来源：XXX（非《储能科学与技术》）”，均转载自其它媒体，转载目的在于传递更多信息，并不代表本网赞同其观点和对其真实性负责。其他媒体如需转载，请与稿件来源方联系，如产生任何问题与本网无关。
地址：北京东城区青年湖南街13号化工出版社3层　电话：86-10-64519601/64519602/64519643　E-mail：[email protected]; [email protected]
京公网安备 11010102001997号 京ICP备12046843号-1